Quantitative time-resolved EPR CIDEP study of the photodecomposition oftrans-azocumene in solution
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چکیده
منابع مشابه
Unravelling the ultrafast photodecomposition mechanism of dibenzoyl peroxide in solution by time-resolved IR spectroscopy.
The ultrafast photo-fragmentation of dibenzoyl peroxide (DBPO) is studied using femtosecond UV excitation at 266 nm and mid-infrared broadband probe pulses to elucidate the dissociation mechanism. With the help of (13)C-labeled DBPO it was possible to unambiguously assign transient IR bands in the fingerprint region to the benzoyloxy radical. Our experiments show that the fragmentation is contr...
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ژورنال
عنوان ژورنال: Applied Magnetic Resonance
سال: 1997
ISSN: 0937-9347,1613-7507
DOI: 10.1007/bf03164126